Challenges and strategies toward long-term stability of lead-free tin-based perovskite solar cells
نویسندگان
چکیده
Abstract Due to their outstanding optoelectronic properties, lead-based halide perovskite materials have been applied as efficient photoactive in solution-processed solar cells. Current record efficiencies offer the promise surpass those of silicon However, uncertainty about potential toxicity and facile dissolution water requires a search for new alternative perovskite-like materials. Thanks foresight scientists experience preparation, remarkable results obtained short period time using lead-free compositions. lower solar-to-energy conversion efficiency long-term stability issues are serious drawbacks that hinder progression these Here, we review analyse strategies literature most promising solutions identify factors limit power tin-based In light current state-of-the-art, perspectives further developing
منابع مشابه
Mixed‐Organic‐Cation Tin Iodide for Lead‐Free Perovskite Solar Cells with an Efficiency of 8.12%
In this work, a fully tin-based, mixed-organic-cation perovskite absorber (FA) x (MA)1-x SnI3 (FA = NH2CH = NH2+, MA = CH3NH3+) for lead-free perovskite solar cells (PSCs) with inverted structure is presented. By optimizing the ratio of FA and MA cations, a maximum power conversion efficiency of 8.12% is achieved for the (FA)0.75(MA)0.25SnI3-based device along with a high open-circuit voltage o...
متن کاملLead-free solid-state organic–inorganic halide perovskite solar cells
Lead-free solution-processed solid-state photovoltaic devices based on methylammonium tin iodide (CH3NH3SnI3) perovskite semiconductor as the light harvester are reported. Featuring an optical bandgap of 1.3 eV, the CH3NH3SnI3 perovskite material can be incorporated into devices with the organic hole-transport layer spiro-OMeTAD and show an absorption onset at 950 nm, which is significantly red...
متن کاملRadiative efficiency of lead iodide based perovskite solar cells
The maximum efficiency of any solar cell can be evaluated in terms of its corresponding ability to emit light. We herein determine the important figure of merit of radiative efficiency for Methylammonium Lead Iodide perovskite solar cells and, to put in context, relate it to an organic photovoltaic (OPV) model device. We evaluate the reciprocity relation between electroluminescence and photovol...
متن کاملStability Issues on Perovskite Solar Cells
Organo lead halide perovskite materials like methylammonium lead iodide (CH3NH3PbI3) and formamidinium lead iodide (HC(NH2)2PbI3) show superb opto-electronic properties. Based on these perovskite light absorbers, power conversion efficiencies of the perovskite solar cells employing hole transporting layers have increased from 9.7% to 20.1% within just three years. Thus, it is apparent that pero...
متن کاملEffects of Annealing Conditions on Mixed Lead Halide Perovskite Solar Cells and Their Thermal Stability Investigation
In this work, efficient mixed organic cation and mixed halide (MA0.7FA0.3Pb(I0.9Br0.1)₃) perovskite solar cells are demonstrated by optimizing annealing conditions. AFM, XRD and PL measurements show that there is a better perovskite film quality for the annealing condition at 100 °C for 30 min. The corresponding device exhibits an optimized PCE of 16.76% with VOC of 1.02 V, JSC of 21.55 mA/cm² ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Communications materials
سال: 2022
ISSN: ['2662-4443']
DOI: https://doi.org/10.1038/s43246-022-00327-2